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CAS No 100-46-9 , phenylmethanamine

  • Name: phenylmethanamine
  • Synonyms: (Phenylmethyl)amine;Benzenemethanamine; 100-46-9; alpha-Aminotoluene; (Aminomethyl)benzene;phenylmethanamine; Monobenzylamine; 1-phenylmethanamine;
  • CAS Registry Number:
  • Transport: UN 2735
  • Melting Point: -30 ºC
  • Flash Point: 72 ºC
  • Boiling Point: 182-185 ºC
  • Density: 0.981
  • Refractive index: 1.5424-1.5444
  • Safety Statements: R21/22;R34
  • Hazard Symbols: C: Corrosive;
  • Flash Point: 72 ºC
  • EINECS: 202-854-1
  • Molecular Weight: 107.15306
  • InchiKey: WGQKYBSKWIADBV-UHFFFAOYSA-N
  • InChI: InChI=1S/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2
  • Risk Statements: S26;S36/37/39;S45
  • Molecular Formula: C7H9N
  • Molecular Structure:CAS No:100-46-9 phenylmethanamine

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References of phenylmethanamine
Title: Benzylamine
CAS Registry Number: 100-46-9
CAS Name: Benzenemethanamine
Synonyms: aminotoluene; phenylmethylamine; moringine
Molecular Formula: C7H9N
Molecular Weight: 107.15
Percent Composition: C 78.46%, H 8.47%, N 13.07%
Literature References: Prepn from benzylchloride and ammonia: Mason, J. Chem. Soc. 63, 1311 (1893); by redn of benzonitrile: Carothers, Jones, J. Am. Chem. Soc. 47, 3051 (1925); from benzyl bromide + acetamide: Erikson, Ber. 59, 2665 (1926); from N-benzylphthalimide + hydrazine hydrate: Ing, Manske, J. Chem. Soc. 129, 2348 (1926). Identity with moringine: Chakravarti, Bull. Calcutta Sch. Trop. Med. 3, 162 (1955); C.A. 50, 16891e (1956).
Properties: Liquid; strongly alkaline reaction. bp 185°; bp12 90°. d419 0.983. nD20 1.5401. Miscible with water, alcohol, ether.
Boiling point: bp 185°; bp12 90°
Index of refraction: nD20 1.5401
Density: d419 0.983
 
Derivative Type: Hydrochloride
Molecular Formula: C7H9N.HCl
Molecular Weight: 143.61
Percent Composition: C 58.54%, H 7.02%, N 9.75%, Cl 24.69%
Properties: Crystals, mp 253°.
Melting point: mp 253°
 
Derivative Type: Hydroiodide
Molecular Formula: C7H9N.HI
Molecular Weight: 235.07
Percent Composition: C 35.77%, H 4.29%, N 5.96%, I 53.99%
Properties: Leaflets, mp 162°.
Melting point: mp 162°
 
CAUTION: Highly irritating to skin, mucous membranes.
Use: In organic synthesis.