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CAS No 101-77-9 , 4-[(4-aminophenyl)methyl]aniline

  • Name: 4-[(4-aminophenyl)methyl]aniline
  • Synonyms: Dianilinomethane; p,p'-Methylenedianiline; 4,4'-DIAMINODIPHENYLMETHANE;4,4'-Methylenedianiline; 101-77-9; Tonox; Methylenedianiline;4-[(4-aminophenyl)methyl]aniline; Dadpm;
  • CAS Registry Number:
  • Transport: UN 2651
  • Melting Point: 88-92 ºC
  • Flash Point: 221 ºC
  • Boiling Point: 398-399 ºC (768 TORR)
  • Density: 1.15
  • Safety Statements: R39/23/24/25;R43;R45;R48/20/21/22;R51/53
  • Hazard Symbols: N: Dangerous for the environment;T: Toxic;
  • Flash Point: 221 ºC
  • EINECS: 202-974-4
  • Molecular Weight: 198.26366
  • InchiKey: YBRVSVVVWCFQMG-UHFFFAOYSA-N
  • InChI: InChI=1S/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,
    14-15H2
  • Risk Statements: S45;S53;S61
  • Molecular Formula: C13H14N2
  • Molecular Structure:CAS No:101-77-9 4-[(4-aminophenyl)methyl]aniline
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101-77-9 4,4''-DIAMINODIPHENYLMETHANE; 97%

  • Germany ABCR GmbH & Co KG [Manufacturer]
  • Tel: +49 721 95061-0
  • Fax: +49 721 95061-80
  • Address: Im Schlehert 10
    76187 Karlsruhe
    Germany ,Germany
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101-77-9 4,4'-Methylenedianiline

  • China Dragon Chemical Group Co.,China []
  • Fax: +86-571-88391332 49-211-550203-10
  • Address: 10/Fl., Jinjiang Building, 111 South Hushu Rd., Hangzhou, China ,China
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101-77-9 BIS-(4-AMINOPHENYL)-METHANE

  • Germany CHEMOS GmbH [Manufacturer]
  • Tel: 0049 9402/9336 0
  • Fax: 0049 9402/9336 13
  • Address: CHEMOS GmbH
    Werner-von-Siemensstr. 3
    93128 Regenstauf
    Germany ,Germany
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101-77-9 Di-anilinomethane

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101-77-9 4,4''-METHYLENE DIANILINE

  • United States Aceto Corp. [Manufacturer]
  • Tel: 516-627-6000
  • Fax: 516-627-6093
  • Address: One Hollow Lane
    Lake Success, NY 11042-1215 ,United States
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101-77-9 4,4-METHYLENEDIANILINE

  • United States Tripletoxygen [Manufacturer]
  • Fax: 713-666-7398
  • Address: Tripletoxygen
    P.O. Box 20650
    Houston, TX 77225-0650 ,United States
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101-77-9 4,4''-METHYLENEDIANILINE

  • Norway Chiron AS [Manufacturer]
  • Tel: +47 73 87 44 90
  • Fax: +47 73 87 44 99
  • Address: Chiron AS
    Stiklestadveien 1
    N-7041 Trondheim
    Norway ,Norway
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101-77-9 F-7008-100MG 2,3-DIAMINOBIPHENYL 2HCL

  • Germany Campro Scientific GmbH [Manufacturer]
  • Tel: +49.(0)30.629.01.89.0 (Germany)/ +31.(0)318.529.437 (Netherlands)
  • Fax: +49.(0)30.629.01.89.89
    +31.(0)318.542.181
  • Address: Campro Scientific GmbH
    Postfach 36 20 65
    D-10972 Berlin
    Germany
    Tel. +49.(0)30.629.01.89.0
    Fax +49.(0)30.629.01.89.89
    info@campro.eu ,Germany
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101-77-9 4,4''-METHYLENEDIANILINE

  • China Simag Chemicals [Manufacturer]
  • Tel: +86 592 2680277
  • Fax: +86 592 2680237
  • Address: Simag Chemicals
    A-9D Atlantic sea view city,
    No.9 Hubin West Rd.,
    Xiamen China. ,China
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101-77-9 CHB85621 4,4-METHYLENEDIANILINE

  • China Chemik Co., Ltd. [Manufacturer]
  • Tel: +86-574-87296330 87298855
  • Fax: +86-574-87297461
  • Address: Chemik Co., Ltd.
    Room 2-225,55 Yunshi Street
    Ningbo 315010, China ,China
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References of 4-[(4-aminophenyl)methyl]aniline
Title: p,p¢-Diaminodiphenylmethane
CAS Registry Number: 101-77-9
CAS Name: 4,4¢-Methylenebis[benzenamine]
Synonyms: 4,4¢-methylenedianiline
Molecular Formula: C13H14N2
Molecular Weight: 198.26
Percent Composition: C 78.75%, H 7.12%, N 14.13%
Literature References: Prepn from aniline and formaldehyde: Scanlon, J. Am. Chem. Soc. 57, 887 (1935); by hydrogenolysis of p,p-diaminobenzophenone with LiAlH4: Conover, Tarbell, ibid. 72, 3586 (1950). Identified as causative agent in clinical outbreak of hepatoxicity called Epping Jaundice: H. Kopelman et al., Br. Med. J. 1, 514 (1966); D. B. McGill, J. D. Motto, N. Engl. J. Med. 291, 278 (1974). Review of toxicology and human exposure: Toxicological Profile for Methylenedianiline (PB99-102568, 1998) 194 pp.
Properties: Crystals from water or benzene. mp 91.5-92°. bp768 398-399°; bp18 257°; bp15 249-253°; bp9 232°. Slightly sol in cold water. Very sol in alcohol, benzene, ether.
Melting point: mp 91.5-92°
Boiling point: bp768 398-399°; bp18 257°; bp15 249-253°; bp9 232°
CAUTION: Potential symptoms of overexposure by ingestion are jaundice, weakness, abdominal pain, nausea, vomiting, anorexia, fever, chills, hepatotoxicity (Kopelman). Direct contact may cause skin irritation (PB99-102568). This substance and its dihydrochloride are reasonably anticipated to be human carcinogens: Report on Carcinogens, Eleventh Edition (PB2005-104914, 2004) p III-169.
Use: As chemical intermediate in prodn of isocyanates and polyisocyantes for prepn of polyurethane foams, Spandex fibers; as curing agent for epoxy resins and urethane elastomers; in production of polyamides; in the determination of tungsten and sulfates; in prepn of azo dyes; as corrosion inhibitor.