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CAS No 108-18-9 , N-propan-2-ylpropan-2-amine

  • Name: N-propan-2-ylpropan-2-amine
  • Synonyms: N-(1-methylethyl)-; DIPA; 2-Propanamine;108-18-9; N,N-Diisopropylamine; N-(1-Methylethyl)-2-propanamine;N-propan-2-ylpropan-2-amine;
  • CAS Registry Number:
  • Transport: UN 1158
  • Melting Point: -61 ºC
  • Flash Point: -7 ºC
  • Boiling Point: 84 ºC
  • Density: 0.716
  • Refractive index: 1.391-1.393
  • Water Solubility: 100 G/L (20 ºC)
  • Safety Statements: R11;R20/22;R34
  • Hazard Symbols: C: Corrosive;F: Flammable;
  • Flash Point: -7 ºC
  • EINECS: 203-558-5
  • Molecular Weight: 101.19
  • InchiKey: UAOMVDZJSHZZME-UHFFFAOYSA-N
  • InChI: InChI=1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3
  • Risk Statements: S16;S26;S36/37/39;S45
  • Molecular Formula: C6H15N
  • Molecular Structure:CAS No:108-18-9 N-propan-2-ylpropan-2-amine
References of N-propan-2-ylpropan-2-amine
Title: Diisopropylamine
CAS Registry Number: 108-18-9
CAS Name: N-(1-Methylethyl)-2-propanamine
Molecular Formula: C6H15N
Molecular Weight: 101.19
Percent Composition: C 71.22%, H 14.94%, N 13.84%
Line Formula: [(CH3)2CH]2NH
Literature References: Prepn: A. Siersch, Ann. 148, 263 (1868); M. Van der Zande, Rec. Trav. Chim. 8, 202 (1889). Enthalpy of formation: M. A. V. Ribeiro da Silva et al., J. Chem. Thermodyn. 29, 1025 (1997). Toxicity study: H. F. Smyth et al., Arch. Ind. Hyg. Occup. Med. 10, 61 (1954). Safety assessment: J. Am. Coll. Toxicol. 14, 182-192 (1995).
Properties: Liquid; characteristic odor; strongly alkaline. d22 0.722. bp 84°. Flash pt, open cup: 21°F (-6°C). Sol in water, alc. LD50 orally in rats: 0.77 g/kg (Smyth).
Boiling point: bp 84°
Flash point: Flash pt, open cup: 21°F (-6°C)
Density: d22 0.722
Toxicity data: LD50 orally in rats: 0.77 g/kg (Smyth)
 
Derivative Type: Lithium salt
CAS Registry Number: 4111-54-0
Synonyms: LDA; lithiodiisopropylamine; lithium diisopropylamide
Literature References: Strong nucleophile. Crystal structure: N. D. R. Barnett et al. J. Am. Chem. Soc. 113, 8187 (1991). Use as nucleophile: Y. Tanaka et al., Bull. Chem. Soc. Jpn. 60, 788 (1987); S. Saito et al., J. Am. Chem. Soc. 119, 611 (1997). Review of chemistry: Reagents for Organic Synthesis vol. 8, M. Fieser, Ed. (Wiley-Interscience, New York, 1980) pp 292-299.
Properties: Powder, melts with decompn. Air and moisture sensitive.
 
CAUTION: Potential symptoms of overexposure are irritation of eyes, skin and respiratory system; nausea, vomiting; headache; visual disturbance. See NIOSH Pocket Guide to Chemical Hazards (DHHS/NIOSH 97-140, 1997) p 110.
Use: pH adjuster in colognes and toilet waters. In organic synthesis, particularly, the lithium salt.