Home > Name List By other > (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[4-[(E)-3-hydroxyprop-1-enyl]-2, 6-dimethoxyphenoxy]oxane-3,4,5-triol

CAS No 118-34-3 , (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[4-[(E)-3-hydroxyprop-1-enyl]-2,
6-dimethoxyphenoxy]oxane-3,4,5-triol

  • Name: (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[4-[(E)-3-hydroxyprop-1-enyl]-2,
    6-dimethoxyphenoxy]oxane-3,4,5-triol
  • Synonyms: MAGNOLENIN A; Syringenin; Lilacin; Syrigin;Eleutheroside B; Methoxyconiferine; CHEBI:9380; Syringoside;(2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[4-[(E)-3-hydroxyprop-1-enyl]-2,
    6-dimethoxyphenoxy]oxane-3,4,5-triol; Ligustrin;
  • CAS Registry Number:
  • Density: 1.415 g/cm3
  • Refractive index: 1.622
  • EINECS: 202-680-6
  • Molecular Weight: 372.36706
  • InchiKey: QJVXKWHHAMZTBY-GCPOEHJPSA-N
  • InChI: InChI=1S/C17H24O9/c1-23-10-6-9(4-3-5-18)7-11(24-2)16(10)26-17-15(22)14
    (21)13(20)12(8-19)25-17/h3-4,6-7,12-15,17-22H,5,8H2,1-2H3/b4-3+/t12-,
    13-,14+,15-,17+/m1/s1
  • Molecular Formula: C17H24O9
  • Molecular Structure:CAS No:118-34-3 (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[4-[(E)-3-hydroxyprop-1-enyl]-2,<br />6-dimethoxyphenoxy]oxane-3,4,5-triol

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References of (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-[4-[(E)-3-hydroxyprop-1-enyl]-2,
6-dimethoxyphenoxy]oxane-3,4,5-triol
Title: Syringin
CAS Registry Number: 118-34-3
CAS Name: (E)-4-(3-Hydroxy-1-propenyl)-2,6-dimethoxyphenyl-b-D-glucopyranoside
Synonyms: 4-(3-hydroxypropenyl)-2,6-dimethoxyphenyl-D-glucoside; syringoside; ligustrin; lilacin; methoxyconiferine
Molecular Formula: C17H24O9
Molecular Weight: 372.37
Percent Composition: C 54.83%, H 6.50%, O 38.67%
Literature References: First isolated by Meillet in 1841 from bark of Syringa vulgaris L. (lilac): Ann. 40, 319 (1841). Prepn: Pauly, Strassberger, Ber. 62, 2277 (1929); Freudenberg, Schraube, Ber. 88, 16 (1955). Isoln from lilac bark: Freudenberg et al., Ber. 84, 472 (1951); from various plants: Plouvier, Compt. Rend. 254,4196 (1962); from cambial sap of spruce: Freudenberg, Harkin, Phytochemistry 2, 189 (1963).
 
Derivative Type: Monohydrate
Properties: Crystals from water, mp 192°. [a]D20 -8.2° (c = 2.43 in chloroform), -17.25° (water). Slightly sol in cold water; sol in hot water, alc. Practically insol in ether.
Melting point: mp 192°
Optical Rotation: [a]D20 -8.2° (c = 2.43 in chloroform), -17.25° (water)