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CAS No 12135-22-7 , palladium(2+)

  • Name: palladium(2+)
  • Synonyms: MolPort-006-119-889; ANW-17591;dihydroxide;palladium(2+); FC0826; CTK0I1946; Palladium hydroxide 20wt.% Pd on carbon;AG-D-46368; AKOS015904338; KSC181S4N;
  • CAS Registry Number:
  • Transport: UN1325
  • Safety Statements: 22-24/25
  • Hazard Symbols: F: Flammable;
  • EINECS: 235-219-2
  • Molecular Weight: 140.43468
  • InchiKey: NXJCBFBQEVOTOW-UHFFFAOYSA-L
  • InChI: InChI=1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
  • Risk Statements: S24/25
  • Molecular Formula: H2O2Pd
  • Molecular Structure:CAS No:12135-22-7 palladium(2+)

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References of palladium(2+)
Title: Pearlman's Catalyst
CAS Registry Number: 12135-22-7
CAS Name: Palladium hydroxide (Pd(OH)2)
Synonyms: palladium hydroxide on carbon
Molecular Formula: H2O2Pd
Molecular Weight: 140.43
Percent Composition: H 1.44%, O 22.79%, Pd 75.78%
Line Formula: Pd(OH)2/C
Literature References: Commercial product contains 20 wt % Pd(OH)2 on carbon. Prepn: W. M. Pearlman, Tetrahedron Lett. 8, 1663 (1967); and catalytic activity study: R. J. Card et al., J. Catal. 79, 13 (1983). Catalytic applications in debenzylating amines: R. C. Bernotas, R. V. Cube, Synth. Commun. 20, 1209 (1990); in Nef-type reactions: T. Capecchi et al., J. Chem. Soc. Perkin Trans. 1 2000, 2681; in Pd-catalyzed coupling reactions: Y. Mori, M. Seki, J. Org. Chem. 68, 1571 (2003); in oxidation of silyl enol ethers: J.-Q. Yu et al., Org. Lett. 7, 1415 (2005).
Use: Nonpyrophoric catalyst for hydrogenolysis of benzyl-nitrogen and benzyl-oxygen bonds.