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CAS No 1271-19-8 , Titanocene dichloride

  • Name: Titanocene dichloride
  • Synonyms: Titanocene dichloride; bis(eta(sup5)-cyclopentadienyl)titaniumdichloride;Bis(cyclopentadienyl)titanium(IV) dichloride;TITANOCENE DICHLORIDE; Di(cyclopentadienyl)titanium(IV) dichloride; Bis(pi-cyclopentadienyl)dichlorotitanium; Bis(pi-cyclopentadienyl)titanium dichloride; Bis(eta(sup5)-cyclopentadienyl)titanium dichloride; bis(cyclopentadienyl)dichlorotitanium; bis(eta(5)-cyclopentadienyl)titaniumdichloride; bis(eta5-Cyclopentadienyl) titanium dichloride;
  • CAS Registry Number:
  • Transport: UN3261
  • Melting Point: 287-289 ºC
  • Density: 1.6
  • Water Solubility: SLOW DECOMPOSITION
  • Safety Statements: R33;R34;R37/38;R40;R61
  • Hazard Symbols: Xi: Irritant;T: Toxic;
  • HS Code: 29310095
  • EINECS: 215-035-9
  • Molecular Weight: 248.97
  • InChI: InChI=1/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q2*-1;;;+4/p-2/r2C5H5.Cl2Ti/c2*1-2-4-5-3-1;1-3-2/h2*1-5H;/q2*-1;+2
  • Risk Statements: S26;S36/37/39;S45;S6A;S7/8
  • Molecular Formula: C10H10Cl2Ti
  • Molecular Structure:CAS No:1271-19-8 Titanocene dichloride

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References of Titanocene dichloride
Title: Titanocene Dichloride
CAS Registry Number: 1271-19-8
CAS Name: Dichlorobis(h5-2,4-cyclopentadien-1-yl)titanium
Synonyms: dichlorodi-p-cyclopentadienyltitanium; biscyclopentadienyltitanium(IV) dichloride
Molecular Formula: C10H10Cl2Ti
Molecular Weight: 248.96
Percent Composition: C 48.24%, H 4.05%, Cl 28.48%, Ti 19.23%
Line Formula: Cp2TiCl2
Literature References: Prepn: Wilkinson, Birmingham, J. Am. Chem. Soc. 76, 4281 (1954). Structure: Clearfield et al., Can. J. Chem. 53, 1622 (1975).
Properties: Bright red acicular crystals from toluene. mp 289 ± 2°. d 1.60. Moderately sol in toluene, chloroform, alcohol, other hydroxylic solvents; sparingly sol in water, petr ether, benzene, ether, carbon disulfide, carbon tetrachloride.
Melting point: mp 289 ± 2°
Density: d 1.60
Use: Catalyst; with aluminum alkyls as Ziegler-Natta polymerization catalyst.