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CAS No 14283-07-9 , lithium

  • Name: lithium
  • Synonyms: lithium borofluoride;tetrafluoroborate; ACMC-209cp3; LITHIUM TETRA FLUOROBORATE;Lithium fluoroborate; LithoTab tetrafluoroborate;lithium; AC1N8NED; 14283-07-9;
  • CAS Registry Number:
  • Transport: UN 3260
  • Melting Point: 293-300 ºC (DEC.)
  • Flash Point: °C
  • Boiling Point: °Cat760mmHg
  • Density: 0.852
  • Refractive index: 1.3332
  • Safety Statements: R20/21/22;R34
  • Hazard Symbols: C: Corrosive;
  • HS Code: 28269090
  • Flash Point: °C
  • EINECS: 238-178-9
  • Molecular Weight: 93.745613
  • InchiKey: UFXJWFBILHTTET-UHFFFAOYSA-N
  • InChI: InChI=1S/BF4.Li/c2-1(3,4)5;/q-1;+1
  • Risk Statements: S25;S36/37/39;S45
  • Molecular Formula: BF4Li
  • Molecular Structure:CAS No:14283-07-9 lithium

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References of lithium
Title: Lithium Tetrafluoroborate
CAS Registry Number: 14283-07-9
Synonyms: Lithium fluoroboride; lithium fluoborate
Molecular Formula: BF4Li
Molecular Weight: 93.75
Percent Composition: B 11.53%, F 81.06%, Li 7.40%
Line Formula: LiBF4
Literature References: Mild Lewis acid. Prepn: P. Baumgarten, W. Bruns, Ber. 72, 1753 (1939); I. Shapiro, H. G. Weiss, J. Am. Chem. Soc. 75, 1753 (1953). NMR structural study: E. C. Reynhardt, J. A. J. Lourens, J. Chem. Phys. 80, 6240 (1984); 19F NMR study of soln behavior: V. N. Plakhotnik et al., J. Fluorine Chem. 98, 133 (1999). Catalytic use in Diels-Alder reactions: D. A. Smith, K. N. Houk, Tetrahedron Lett. 32, 1549 (1991); J. S. Yadav et al., Synthesis 2001, 1065. Review of applications in organic synthesis: B. S. Babu, K. K. Balasubramanian, Acros Org. Acta 7, 1-3 (2000).
Properties: White, crystalline, hygroscopic solid. Sol in water, methanol, acetonitrile. Soly in ether at 25°: 1.3 g/100 ml.
Use: Catalyst in organic synthesis; electrolyte for lithium ion batteries.