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CAS No 15656-28-7 , iodanium Search by region : China

  • Name: iodanium
  • Synonyms: 15656-28-7;tetrafluoroborate;pyridine;iodanium;Bis(pyridine)iodonium tetrafluoroborate; 531634_ALDRICH; iodanium pyridine tetrafluoroborate;
  • CAS Registry Number:
  • Melting Point: 137-141 ºC
  • Flash Point: °C
  • Boiling Point: °Cat760mmHg
  • Density: g/cm3
  • Safety Statements: R36/37/38
  • Hazard Symbols: Xi: Irritant;
  • Flash Point: °C
  • Molecular Weight: 373.924763
  • InchiKey: WVXJCTSZJWIBQT-UHFFFAOYSA-N
  • InChI: InChI=1S/2C5H5N.BF4.H2I/c2*1-2-4-6-5-3-1;2-1(3,
    4)5;/h2*1-5H;;1H2/q;;-1;+1
  • Risk Statements: S26;S37/39
  • Molecular Formula: C10H12BF4IN2
  • Molecular Structure:CAS No:15656-28-7 iodanium

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References of iodanium
Title: Bis(pyridine)iodonium Tetrafluoroborate
CAS Registry Number: 15656-28-7
CAS Name: Bis(pyridine)iodine(1+) tetrafluoroborate(1-)
Synonyms: Barluenga's reagent; IPy2BF4
Molecular Formula: C10H10IN2.BF4
Molecular Weight: 371.91
Percent Composition: C 32.29%, H 2.71%, I 34.12%, N 7.53%, B 2.91%, F 20.43%
Literature References: Mild source of iodonium ions in organic synthesis. Prepn: J. Barluenga et al., Angew. Chem. Int. Ed. 24, 319 (1985). Oxidation of alcohols: idem et al., Chem. Eur. J. 10, 4206 (2004). Brief review: K. Mu?iz, Synlett 1999, 1679. Review of iodination chemistry: J. Barluenga, Pure Appl. Chem. 71, 431-436 (1999).
Properties: Crystals from dichloromethane, mp 149-151° (dec). Store under inert atmosphere at 4° in the dark.
Melting point: mp 149-151°
Use: Iodination and oxidation reagent.