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CAS No 2712-78-9 , [phenyl-(2,2,2-trifluoroacetyl)oxy-λ Search by region : France

  • Name: [phenyl-(2,2,2-trifluoroacetyl)oxy-λ
  • Synonyms: PIFA; Phenylbis(trifluoroacetato-O)iodine;[Bis(trifluoroacetoxy)iodo]benzene; bis(trifluoracetoxy)- iodobenzene; 2712-78-9;3-iodanyl]
    2,2,2-trifluoroacetate;[phenyl-(2,2,2-trifluoroacetyl)oxy-λ SBB057936; (Bis(trifluoroacetoxy)iodo)benzene;
  • CAS Registry Number:
  • Melting Point: 121-125 ºC
  • Flash Point: 115.624°C
  • Boiling Point: 267.573°C at 760 mmHg
  • Density: 1.95g/cm3
  • Refractive index: 1.483
  • Safety Statements: R36/37/38
  • Hazard Symbols: Xi: Irritant;
  • HS Code: 29036990
  • Flash Point: 115.624°C
  • EINECS: 220-308-0
  • Molecular Weight: 430.039189
  • InchiKey: PEZNEXFPRSOYPL-UHFFFAOYSA-N
  • InChI: InChI=1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,
    15)16/h1-5H
  • Risk Statements: S26;S37/39
  • Molecular Formula: C10H5F6IO4
  • Molecular Structure:CAS No:2712-78-9 [phenyl-(2,2,2-trifluoroacetyl)oxy-λ

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References of [phenyl-(2,2,2-trifluoroacetyl)oxy-λ
Title: Phenyliodine(III) Bis(trifluoroacetate)
CAS Registry Number: 2712-78-9
CAS Name: Phenylbis(trifluoroacetato-kO)iodine
Synonyms: bis(trifluoroacetoxy)iodobenzene; iodobenzene ditrifluoroacetate; PIFA
Literature References: Hypervalent iodine(III) reagent. Prepn: N. W. Alcock, T. C. Waddington, J. Chem. Soc. 1963, 4103; I. I. Maletina et al., J. Org. Chem. USSR 10, 294 (1974). Structural study: N. W. Alcock et al., J. Chem. Soc. Dalton Trans. 1984, 1709. Use as a one-electron oxidant: L. Eberson et al., Acta Chem. Scand. 49, 640 (1995). Review of applications in organic synthesis: G. Pohnert, J. Prakt. Chem. 342, 731-734 (2000).
Properties: Crystals from chloroform + petroleum ether, mp 120-121°.
Melting point: Crystals from chloroform + petroleum ether, mp 120-121°
Use: In oxidation, cyclization, dehydrogenation, and dearomatization reactions.