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CAS No 536-80-1 , iodosylbenzene Search by region : Germany

  • Name: iodosylbenzene
  • Synonyms: 536-80-1;iodosylbenzene; iodosyl-; AI3-03642; BRN 1923474; iodoso-; Benzene; 125509-11-7; EINECS 208-648-8; NSC 406477;Iodosylbenzene;
  • CAS Registry Number:
  • Transport: 1479
  • Safety Statements: Poison by intraperitoneal and intravenous routes. Explodes when heated to 210°C. When heated to decomposition it emits toxic fumes of I−.
  • EINECS: 208-648-8
  • Molecular Weight: 220.00777
  • InchiKey: JYJVVHFRSFVEJM-UHFFFAOYSA-N
  • InChI: InChI=1S/C6H5IO/c8-7-6-4-2-1-3-5-6/h1-5H
  • Molecular Formula: C6H5IO
  • Molecular Structure:CAS No:536-80-1 iodosylbenzene

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536-80-1 IODOSYLBENZENE

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References of iodosylbenzene
Title: Iodosobenzene
CAS Registry Number: 536-80-1
CAS Name: Iodosylbenzene
Synonyms: PhIO
Molecular Formula: C6H5IO
Molecular Weight: 220.01
Percent Composition: C 32.75%, H 2.29%, I 57.68%, O 7.27%
Literature References: Versatile oxidizing agent. Prepn: C. Willgerodt, Ber. 26, 357 (1893). Synthesis: H. Saltzman, J. G. Sharefkin, Org. Synth. 5, 658 (1973). Mechanistic study: R. M. Moriarty et al., J. Am. Chem. Soc. 103, 686 (1981). Use as oxidant: S. Mukerjee et al., ibid. 119, 8097 (1997); G. Mielniczak, A. Lopusinski, Synlett 2001, 505; as mediator: P. Dauban et al., J. Am. Chem. Soc. 123, 7707 (2001); C.-C. Guo et al., Appl. Catal. A 230, 53 (2002). Brief review: A. Minatti, Synlett 2003, 140-141.
Properties: Yellowish amorphous powder. Explosive if heated to 210° due to disproportion into phenyliodide and iodylbenzene.
Use: Oxygen transfer reagent for stiochiometric or catalytic cross-functionalization of alkenes, alcohols, sulfides, and organometallo compds.