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CAS No 556-91-2 , aluminium tri-tert-butanolate

  • Name: aluminium tri-tert-butanolate
  • Synonyms: tert-Butylalcohol, aluminum salt (8CI);Aluminum tert-butylate; Aluminum tert-butoxide (6CI,7CI); Aluminum tert-butanolate;Tris(2-methyl-2-propanolato)aluminum;2-Propanol,2-methyl-, aluminum salt (9CI);aluminium tri-tert-butanolate; Aluminum t-butoxide; Aluminum tris(tert-butylate); Aluminum tri-tert-butoxide; Tri-tert-butoxyaluminum; Aluminumtris(tert-butoxide);
  • CAS Registry Number:
  • Transport: UN 2925 4.1/PG 2
  • Melting Point: 241°C
  • Density: 0.804 g/cm3
  • Safety Statements: S8S16S26S45S36/S37/S39
  • Hazard Symbols: F,C
  • EINECS: 209-146-1
  • Molecular Weight: 246.324
  • InChI: InChI=1/3C4H9O.Al/c3*1-4(2,3)5;/h3*1-3H3;/q3*-1;+3
  • Risk Statements: 11-34
  • Molecular Formula: C4H10O?1/3Al
  • Molecular Structure:CAS No:556-91-2 aluminium tri-tert-butanolate

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References of aluminium tri-tert-butanolate
Title: Aluminum tert-Butoxide
CAS Registry Number: 556-91-2
CAS Name: 2-Methyl-2-propanol aluminum salt
Molecular Formula: C12H27AlO3
Molecular Weight: 246.32
Percent Composition: C 58.51%, H 11.05%, Al 10.95%, O 19.49%
Line Formula: Al[OC(CH3)3]3
Literature References: Prepd from aluminum tert-butyl alcohol and mercuric chloride: Wayne, Adkins, Org. Synth. coll. vol. III, 48 (1955).
Properties: Powder; can be recryst from benzene. Sublimes at 180°. Pure compd does not melt or decomp upon heating up to 300° in a sealed tube, but traces of moisture or tert-butyl alc cause it to melt at 160-200°. Very sol in organic solvents; approx 9 g dissolves in 5 g ethyl propionate at 120°.
Use: Reagent for oxidation of alcohols to ketones; in dealcoholation of orthoesters.