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CAS No 620-13-3 , 1-(bromomethyl)-3-methylbenzene

  • Name: 1-(bromomethyl)-3-methylbenzene
  • Synonyms: m-Methylbenzyl bromide; M-XYLYL BROMIDE;1-(Bromomethyl)-3-methylbenzene; alpha-Bromo-m-xylene; 620-13-3; 3-(Bromomethyl)toluene;1-(bromomethyl)-3-methylbenzene;
  • CAS Registry Number:
  • Transport: UN 1701
  • Melting Point: 18
  • Flash Point: 82 ºC
  • Boiling Point: 185 ºC (340 MMHG)
  • Density: 1.37
  • Refractive index: 1.564-1.568
  • Safety Statements: R20/21/22;R34
  • Hazard Symbols: C: Corrosive;
  • Flash Point: 82 ºC
  • EINECS: 210-625-2
  • Molecular Weight: 185.06106
  • InchiKey: FWLWTILKTABGKQ-UHFFFAOYSA-N
  • InChI: InChI=1S/C8H9Br/c1-7-3-2-4-8(5-7)6-9/h2-5H,6H2,1H3
  • Risk Statements: S26;S36/37/39;S45
  • Molecular Formula: C8H9Br
  • Molecular Structure:CAS No:620-13-3 1-(bromomethyl)-3-methylbenzene

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620-13-3 1-(BROMOMETHYL)-3-METHYLBENZENE

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620-13-3 alpha-Bromo-m-Xylene

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References of 1-(bromomethyl)-3-methylbenzene
Title: Xylyl Bromide
Molecular Formula: C8H9Br
Molecular Weight: 185.06
Percent Composition: C 51.92%, H 4.90%, Br 43.18%
Literature References: Prepn of m-isomer: Wenner, J. Org. Chem. 17, 523 (1952); of o-isomer: Dev, J. Indian Chem. Soc. 32, 403 (1955); of p-isomer: Cockburn et al., J. Chem. Soc. 1960, 3340.
 
Derivative Type: m-Xylyl bromide
CAS Registry Number: 620-13-3
CAS Name: 1-(Bromomethyl)-3-methylbenzene
Synonyms: a-bromo-m-xylene; m-methylbenzyl bromide; w-bromo-m-xylene
Properties: Liquid, bp 212-215° with slight dec. d23 1.371. Practically insol in water; sol in alcohol, ether.
Boiling point: bp 212-215° with slight dec
Density: d23 1.371
 
Derivative Type: o-Xylyl bromide
CAS Registry Number: 89-92-9
Properties: Prisms, mp 21°. bp 223-234°, bp742 216-217°, bp15 102°. nD27 1.5730. d23 1.381. Practically insol in water. Sol in alcohol, ether.
Melting point: mp 21°
Boiling point: bp 223-234°; bp742 216-217°; bp15 102°
Index of refraction: nD27 1.5730
Density: d23 1.381
 
Derivative Type: p-Xylyl bromide
CAS Registry Number: 104-81-4
Properties: Needles from alcohol, mp 38°. bp740 218-220°, bp15 120°. d 1.324. Practically insol in water. Very sol in chloroform, hot ether.
Melting point: mp 38°
Boiling point: bp740 218-220°; bp15 120°
Density: d 1.324
 
CAUTION: Powerful lacrimator.
Use: In organic syntheses; in war-gas formulations.