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CAS No 770-12-7 , dichlorophosphoryloxybenzene Search by region : Germany

  • Name: dichlorophosphoryloxybenzene
  • Synonyms: Dichlorophenoxyphosphine oxide;dichlorophosphoryloxybenzene; phenyl ester; Phosphorodichloridic acid;Phenyl phosphorodichloridate; 770-12-7;
  • CAS Registry Number:
  • Transport: UN 1760
  • Melting Point: -1 ºC
  • Boiling Point: 241-243 ºC
  • Density: 1.412
  • Refractive index: 1.521-1.523
  • Safety Statements: R34
  • Hazard Symbols: C: Corrosive;
  • HS Code: 29209085
  • EINECS: 212-220-6
  • Molecular Weight: 210.982462
  • InchiKey: TXFOLHZMICYNRM-UHFFFAOYSA-N
  • InChI: InChI=1S/C6H5Cl2O2P/c7-11(8,9)10-6-4-2-1-3-5-6/h1-5H
  • Risk Statements: S26;S36/37/39;S45
  • Molecular Formula: C6H5Cl2O2P
  • Molecular Structure:CAS No:770-12-7 dichlorophosphoryloxybenzene

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References of dichlorophosphoryloxybenzene
Title: Phenyl Dichlorophosphate
CAS Registry Number: 770-12-7
CAS Name: Phosphorodichloridic acid phenyl ester
Synonyms: PCDP
Molecular Formula: C6H5Cl2O2P
Molecular Weight: 210.98
Percent Composition: C 34.16%, H 2.39%, Cl 33.61%, O 15.17%, P 14.68%
Literature References: Phosphorylation reagent. Prepn: G. Jacobsen, Ber. 8, 1519 (1875); R. Anschütz, W. O Emery, Ann. 253, 105 (1889). Activation of carboxyl groups: H.-J. Liu, S. I. Sabesan, Can. J. Chem. 58, 2645 (1980); for lactam synthesis: J. M. Aizpurua et al., Tetrahedron Lett. 25, 3905 (1984); L. Banfi, G. Guanti, ibid. 43, 7427 (2002). Oxidative rearrangements: H.-J. Liu, J. M. Nyangulu, ibid. 30, 5097 (1989); J. P. Jeyadevan et al., J. Med. Chem. 47, 1290 (2004). Brief review: A. K. Adak, Synlett 2004, 1651-1652.
Properties: Liquid, bp9mmHg 103-106°; bp13-14mm 116°. d420 1.41214.
Boiling point: Liquid, bp9mmHg 103-106°; bp13-14mm 116°
Density: d420 1.41214
Use: In organic synthesis for preparation of lactams, phosphate diesters and for oxidation reactions.