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CAS No 87413-09-0 , (1,1-diacetyloxy-3-oxo-1λ Search by region : Netherlands

  • Name: (1,1-diacetyloxy-3-oxo-1λ
  • Synonyms: 5,2-benziodoxol-1-yl) acetate;(1,1-diacetyloxy-3-oxo-1λ 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one; 87413-09-0; dess-martin reagent;Dess-Martin periodinane; Dess-Martinperiodinane;
  • CAS Registry Number:
  • Transport: UN 1593 6
  • Melting Point: 130-133 ºC
  • Density: 1.362
  • Safety Statements: R40;R8
  • Hazard Symbols: O: Oxidizing agent;Xn: Harmful;
  • Molecular Weight: 424.14199
  • InchiKey: NKLCNNUWBJBICK-UHFFFAOYSA-N
  • InChI: InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,
    21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
  • Risk Statements: S17;S23;S24/25;S36/37
  • Molecular Formula: C13H13IO8
  • Molecular Structure:CAS No:87413-09-0 (1,1-diacetyloxy-3-oxo-1λ

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87413-09-0 Dess-Martin periodinane

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References of (1,1-diacetyloxy-3-oxo-1λ
Title: Dess-Martin Periodinane
CAS Registry Number: 87413-09-0
CAS Name: 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Synonyms: triacetoxyperiodinane
Molecular Formula: C13H13IO8
Molecular Weight: 424.14
Percent Composition: C 36.81%, H 3.09%, I 29.92%, O 30.18%
Literature References: Pentacoordinate organoiodine (periodinane); selectively oxidizes primary and secondary alcohols, aldehydes and ketones. Prepn: D. B. Dess, J. C. Martin, J. Org. Chem. 48, 4155 (1983); R. E. Ireland, L. Liu, ibid. 58, 2899 (1993). Structure and reaction conditions: D. B. Dess, J. C. Martin, J. Am. Chem. Soc. 113, 7277 (1991); acceleration by water: S. D. Meyer, S. L. Schreiber, J. Org. Chem. 59, 7549 (1994). Synthetic applications: N. E. Jenkins et al., Synth. Commun. 30, 947 (2000); A. G. Myers et al., Tetrahedron Lett. 41, 1359 (2000).
Properties: White crystalline solid, mp 134°. Sparingly sol in hexane or ether. Sol in chloroform, methylene chloride, acetonitrile and acetone.
Melting point: mp 134°
Use: Oxidizing reagent.