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CAS No 13746-98-0 , Nitric acid,thallium(3+) salt (3:1)

  • Name: Nitric acid,thallium(3+) salt (3:1)
  • Synonyms: Thallium nitrate (Tl(NO3)3); Thallic nitrate;Nitricacid, thallium(3+) salt (8CI,9CI); Thallium nitrate (7CI); Thallium(III) nitrate; Thallium trinitrate;Nitric acid,thallium(3+) salt (3:1);
  • CAS Registry Number:
  • Flash Point: °C
  • Boiling Point: 83°Cat760mmHg
  • Density: g/cm3
  • Safety Statements: A poison by skin contact. When heated to decomposition it emits toxic vapors of Tl.
  • Hazard Symbols: A poison by skin contact.
  • Flash Point: °C
  • EINECS: 237-325-4
  • Molecular Weight: 390.40
  • InChI: InChI=1/3NO3.3Tl/c3*2-1(3)4;;;/q3*-1;3*+1
  • Molecular Formula: HN O3 . 1/3 Tl
  • Molecular Structure:CAS No:13746-98-0 Nitric acid,thallium(3+) salt (3:1)

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13746-98-0 Nitric acid,thallium(3+) salt (3:1)

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References of Nitric acid,thallium(3+) salt (3:1)
Title: Thallium Trinitrate
CAS Registry Number: 13746-98-0
CAS Name: Nitric acid thallium (3+) salt
Synonyms: thallium(III) nitrate
Molecular Formula: TlN3O9
Molecular Weight: 390.40
Percent Composition: Tl 52.35%, N 10.76%, O 36.88%
Line Formula: Tl(NO3)3
Literature References: Oxidizing reagent. Prepn and use for olefin rearrangement: A. McKillop et al., Tetrahedron Lett. 1970, 5275. Review of early uses: idem, E. C. Taylor, Endeavour 35, 88-93 (1976). Phenolic oxidation for isodityrosine functionality: K. Nakamura et al., Tetrahedron Lett. 42, 6311 (2001); promotion of ring contractions for indans: H. M. C. Ferraz et al., Tetrahedron 57, 1709 (2001). Review: idem et al., Synthesis 1999, 2001-2023; T. O. Vieira, Synlett 2002, 1017-1018.
Properties: Colorless crystals. Readily sol in methanol, dilute mineral acids and mixed sovent systems such as aqueous glyme.
Use: In organic syntheses for a wide variety of oxidations including rearrangement of ketones, olefins, electrophilic cyclization transformations, phenolic oxidative couplings and hydrolysis of dithianes.