Home > Name List By r > rhodium

CAS No 14694-95-2 , rhodium

  • Name: rhodium
  • Synonyms: 14694-95-2;Tris(triphenylphosphine)chlororhodium; AG-D-91592;chloride;rhodium;triphenylphosphane; Chlorotris(triphenylphosphine)rhodium(I);
  • CAS Registry Number:
  • Melting Point: 245-250 ºC
  • Flash Point: 181.7°C
  • Density: g/cm3
  • Safety Statements: R36/38
  • Hazard Symbols: Xi: Irritant;
  • HS Code: 28439090
  • Flash Point: 181.7°C
  • EINECS: 238-744-5
  • Molecular Weight: 925.214886
  • InchiKey: QBERHIJABFXGRZ-UHFFFAOYSA-M
  • InChI: InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-
    8-3-9-15-18;;/h3*1-15H;1H;/p-1
  • Risk Statements: S15;S26;S28A;S37/39
  • Molecular Formula: C54H45ClP3Rh-
  • Molecular Structure:CAS No:14694-95-2 rhodium
Search by region :

Select to

14694-95-2 CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I); 99% WILKINSON''S CATALYST

  • Germany ABCR GmbH & Co KG [Manufacturer]
  • Tel: +49 721 95061-0
  • Fax: +49 721 95061-80
  • Address: Im Schlehert 10
    76187 Karlsruhe
    Germany ,Germany
Contact Supplier

14694-95-2 CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I), 99% WILKINSON''S CATALYST

  • Hong kong Advanced Technology & Industrial Co., Ltd. [Manufacturer]
  • Tel: (852) 2390 2293/ (852) 2394 5546
  • Fax: (852) 2789 8314
  • Address: Unit B, 1/F., Cheong Shing Bldg.,
    17 Walnut St., Tai Kok Tsui, Kln,
    Hong Kong ,Hong kong
Contact Supplier

14694-95-2 100305 CHLORO-TRIS-(TRIPHENYLPHOSPHINE)-RHODIUM-(I)

  • Germany chemcube UG [Manufacturer]
  • Tel: +49 (22 08) 7 75 04 06
  • Fax: +49 (22 08) 7 75 02 30 /
    +49 (32 12) 1 00 74 76
  • Address: chemcube UG
    Salierweg 1
    53859 Niederkassel
    Germany ,Germany
Contact Supplier

14694-95-2 Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)-

  • Germany Merck Schuchardt OHG [Manufacturers]
  • Tel: +49-(8102)-802-0
  • Fax: +49-(8102)-802-175
  • Address: Eduard-Buchner-Str. 14-20, Hohenbrunn 85662, Hohenbrunn,HohenbrunnGermany
Contact Supplier

14694-95-2 Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)-

  • China Shanghai Hanhong Chemical Co., Ltd. [, Manufacturer, Trading Company, Agent]
  • Tel: +86-(21)-64762736, 64531573
  • Fax: +86-(21)-54291107
  • Address: 206-209, NO.1 Building , NO.245,Jiachuan Road, Xuhui District, Shanghai, Xuhui District,ShanghaiChina
Contact Supplier

14694-95-2; 16592-65-7 Chlorotris(triphenylphosphine)rhodium(I)

  • United States MV Laboratories, Inc. [Manufacturer]
  • Tel: 908-788-6906
  • Fax: 908-788-1746
  • Address: MV Laboratories, Inc.
    843 Route 12 West, Suite B17
    Frenchtown, NJ 08825 ,United States
Contact Supplier

14694-95-2 Chlorotris(triphenylphosphine)rhodium(I)

  • China Ningbo Inno Pharmchem Co., Ltd. [Manufacturers]
  • Tel: +86-(574)-87319282
  • Fax: +86-(574)-56877908
  • Address: 5F, Building 4, 1035 Guangxian Rd., Ningbo Hi-Tech Park, Ningbo, Zhejiang 315040, Ningbo,ZhejiangChina
Contact Supplier

14694-95-2 Tris(Triphenylphosphine)Rhodium(I) Chloride

  • China Ruiyuan Group Limited [Manufacturers]
  • Tel: +86-21-50456736
  • Fax: +86-21-60853441
  • Address: No.188, Zhangyang Road, Pudong, Shanghai 200122, ,China
Contact Supplier

14694-95-2 Tris(Triphenylphosphine)Rhodium(I) Chloride

  • China Xilin Chemical Group Co., Ltd []
  • Tel: +86-(0)-15527136576
  • Fax: +86-(27)-83820093
  • Address: 16# Luojiashan, Wuchang District, Wuhan, Hubei 430071, ,China
Contact Supplier

14694-95-2 Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)-

Contact Supplier

Select to

References of rhodium
Title: Wilkinson's Catalyst
CAS Registry Number: 14694-95-2
CAS Name: (SP-4-2)-Chlorotris(triphenylphosphine)rhodium
Molecular Formula: C54H45ClP3Rh
Molecular Weight: 925.21
Percent Composition: C 70.10%, H 4.90%, Cl 3.83%, P 10.04%, Rh 11.12%
Literature References: Dimorphic compd exists in two forms, red and orange, both possess the same chemical properties. Prepn: J. F. Young et al., Chem. Commun. 1965, 131; J. A. Osborn, G. Wilkinson, Inorg. Synth. 10, 67 (1967); eidem, ibid. 28, 77 (1990). Crystal structure: M. J. Bennett, P. B. Donaldson, Inorg. Chem. 16, 655 (1977). Structure and properties: Y. Nishihara et al., Organometallics 21, 825 (2002). Mechanistic study: S. B. Duckett et al., J. Am. Chem. Soc. 116, 10548 (1994). Reduction of nitrobenzenes: H. R. Brinkman et al., Synth. Commun. 26, 973 (1996); selective hydrogenation of olefins: A. Jourdant et al., J. Org. Chem. 67, 3163 (2002). Comprehensive review of properties and reactions: F. H. Jardine, Prog. Inorg. Chem. 28, 63-202 (1981); of hydrogenations: F. Joo, Acc. Chem. Res. 35, 738-745 (2002).
Properties: Dark, burgundy-red crystals from hot ethanol. Orange crystals from < 200 ml ethanol soln refluxed for five minutes; converted to red form on further refluxing. mp 157°. Soly in chloroform, dichloromethane (25°): ~20 g/l; in benzene, toluene (25°): ~2 g/l; much less sol in acetic acid, acetone and other ketones, methanol, lower aliphatic alcohols. Virtually insol in alkanes and cyclohexane. Donor solvents such as pyridine, dimethyl sulfoxide, acetonitrile dissolve the complex with reaction. Solns are air sensitive. Orange form d 1.363; red form d 1.379.
Melting point: mp 157°
Density: d 1.363; d 1.379
Use: Homogeneous hydrogenation catalyst.