Home > Name List By 4 > 4,21-Dioxabicyclo[15.3.1]heneicosa-9,15,18-trien-3-one,11-[[3-O-(aminocarbonyl)-2,6-dideoxy-b-D-arabino-hexopyranosyl]oxy]-1-...

CAS No 33538-71-5 , 4,21-Dioxabicyclo[15.3.1]heneicosa-9,15,18-trien-3-one,11-[[3-O-(aminocarbonyl)-2,6-dideoxy-b-D-arabino-hexopyranosyl]oxy]-1-hydroxy-5-[(1R,3R,4S,5S)-4-hydroxy-1,3,5-trimethyl-6-oxooctyl]-6,8,16,18-tetramethyl-,(1R,5S,6R,8R,9E,11R,15E,17R)- (9CI)

  • Name: 4,21-Dioxabicyclo[15.3.1]heneicosa-9,15,18-trien-3-one,11-[[3-O-(aminocarbonyl)-2,6-dideoxy-b-D-arabino-hexopyranosyl]oxy]-1-hydroxy-5-[(1R,3R,4S,5S)-4-hydroxy-1,3,5-trimethyl-6-oxooctyl]-6,8,16,18-tetramethyl-,(1R,5S,6R,8R,9E,11R,15E,17R)- (9CI)
  • Synonyms: Aabomycin A1;VenturicidinA (8CI);4,21-Dioxabicyclo[15.3.1]heneicosa-9,15,18-trien-3-one,11-[[3-O-(aminocarbonyl)-2,6-dideoxy-b-D-arabino-hexopyranosyl]oxy]-1-hydroxy-5-[(1R,3R,4S,5S)-4-hydroxy-1,3,5-trimethyl-6-oxooctyl]-6,8,16,18-tetramethyl-,(1R,5S,6R,8R,9E,11R,15E,17R)- (9CI); 4,21-Dioxabicyclo[15.3.1]heneicosane,venturicidin B deriv.; Venturicidin B, 3'-carbamate;
  • CAS Registry Number:
  • Flash Point: 482.9°C
  • Boiling Point: 874.9°Cat760mmHg
  • Density: 1.16g/cm3
  • Refractive index: 1.541
  • Safety Statements:
    RTECS YX4556000
  • Flash Point: 482.9°C
  • EINECS: 251-568-3
  • Molecular Weight: 749.97
  • InChI: InChI=1/C41H67NO11/c1-10-32(43)29(8)36(45)26(5)20-28(7)38-27(6)19-23(2)15-16-31(50-35-21-33(51-40(42)47)37(46)30(9)49-35)14-12-11-13-24(3)39-25(4)17-18-41(48,53-39)22-34(44)52-38/h13,15-17,23,26-31,33,35-39,45-46,48H,10-12,14,18-22H2,1-9H3,(H2,42,47)/b16-15+,24-13+/t23-,26+,27+,28+,29+,30+,31+,33+,35-,36-,37+,38-,39+,41+/m0/s1
  • Molecular Formula: C41H67 N O11
  • Molecular Structure:CAS No:33538-71-5 4,21-Dioxabicyclo[15.3.1]heneicosa-9,15,18-trien-3-one,11-[[3-O-(aminocarbonyl)-2,6-dideoxy-b-D-arabino-hexopyranosyl]oxy]-1-hydroxy-5-[(1R,3R,4S,5S)-4-hydroxy-1,3,5-trimethyl-6-oxooctyl]-6,8,16,18-tetramethyl-,(1R,5S,6R,8R,9E,11R,15E,17R)- (9CI)

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33538-71-5 VENTURICIDIN A

  • Germany Cfm Oskar Tropitzsch [Manufacturer]
  • Tel: +49-9231-9619-0
  • Fax: +49-9231-9619-60
  • Address: Cfm Oskar Tropitzsch
    Waldershofer Str. 49-51
    95615 Marktredwitz
    Germany null,nullGermany
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33538-71-5 VENTURICIDIN A

  • China Nanjing Chemlin Chemical Industry Co.,Ltd. [Manufacturer]
  • Tel: +86 25 8369-7070/ +86 138 51816776 (Mobile)
  • Fax: +86 25 8345-3275
  • Address: Rm.902 Longyin Plaza,
    No. 217 Zhongshan Rd.
    (N)Nanjing 210009,China null,nullChina
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References of 4,21-Dioxabicyclo[15.3.1]heneicosa-9,15,18-trien-3-one,11-[[3-O-(aminocarbonyl)-2,6-dideoxy-b-D-arabino-hexopyranosyl]oxy]-1-hydroxy-5-[(1R,3R,4S,5S)-4-hydroxy-1,3,5-trimethyl-6-oxooctyl]-6,8,16,18-tetramethyl-,(1R,5S,6R,8R,9E,11R,15E,17R)- (9CI)
Title: Venturicidins
Literature References: Antifungal antibiotics isolated from Streptomyces aureofaciens strains. Preliminary isolation work: Rhodes et al., Nature 192, 952 (1962). Isoln of venturicidins A and B and activity studies: Brufani et al., Helv. Chim. Acta 51, 1293 (1968); see also Langcake et al., Biochem. Soc. Trans. 2, 202 (1974). Final structures: Brufani et al., Experientia 27, 604 (1971); eidem, Helv. Chim. Acta 55, 2329 (1972).
 
Derivative Type: Venturicidin A
CAS Registry Number: 33538-71-5
CAS Name: Venturicidin B 3¢-carbamate
Molecular Formula: C41H67NO11
Molecular Weight: 749.97
Percent Composition: C 65.66%, H 9.00%, N 1.87%, O 23.47%
Properties: Needles from chloroform-petr ether, mp 145-147°. Also reported as mp 140-142°. [a]D +119° (c = 0.5 in chloroform). uv max (alcohol): 206, 247 (shoulder), ~300 nm (shoulder) (log e 3.80, 2.23, 2.08).
Melting point: mp 145-147°; mp 140-142°
Optical Rotation: [a]D +119° (c = 0.5 in chloroform)
Absorption maximum: uv max (alcohol): 206, 247 (shoulder), ~300 nm (shoulder) (log e 3.80, 2.23, 2.08)
 
Derivative Type: Venturicidin B
CAS Registry Number: 33538-72-6
Synonyms: (3-Decarbamoyloxy)-3-hydroxyventuricidin A
Molecular Formula: C40H66O10
Molecular Weight: 706.95
Percent Composition: C 67.96%, H 9.41%, O 22.63%
Properties: Amorphous white powder from chloroform-ether, mp 168-170°. Also reported as mp 145-149° (ethyl acetate-petr ether). [a]D +100° (c = 0.847 in chloroform).
Melting point: mp 168-170°; mp 145-149° (ethyl acetate-petr ether)
Optical Rotation: [a]D +100° (c = 0.847 in chloroform)