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CAS No 76-49-3 , (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) acetate

  • Name: (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) acetate
  • Synonyms: Bornyl ethanoate;(4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) acetate; endo-bornyl acetate; acetate; Bornyl acetic ether; 2-Camphanol acetate;Borneol; 2-Camphanyl acetate;
  • CAS Registry Number:
  • Melting Point: 27
  • Flash Point: 192 ºF
  • Boiling Point: 228-231 ºC
  • Density: 0.985
  • Refractive index: 1.4635
  • Alpha: -41 º (NEAT)
  • Water Solubility: Slightly soluble in water; Insoluble in glycerin, propylene glycol
  • Safety Statements: Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
  • Flash Point: 192 ºF
  • EINECS: 200-964-4
  • Molecular Weight: 196.286
  • InchiKey: KGEKLUUHTZCSIP-UHFFFAOYSA-N
  • InChI: InChI=1S/C12H20O2/c1-8(13)14-10-7-9-5-6-12(10,4)11(9,2)3/h9-10H,5-7H2,
    1-4H3
  • Molecular Formula: C12H20O2
  • Molecular Structure:CAS No:76-49-3 (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) acetate

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References of (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) acetate
Title: Bornyl Acetate
CAS Registry Number: 76-49-3
CAS Name: 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol acetate
Synonyms: borneol acetate
Molecular Formula: C12H20O2
Molecular Weight: 196.29
Percent Composition: C 73.43%, H 10.27%, O 16.30%
Line Formula: CH3COOC10H17
Literature References: Prepn of the d-form by acylation of d-borneol: Shishido et al., J. Am. Chem. Soc. 82, 125 (1960).
 
Derivative Type: d-Form
Properties: Crystals, mp 29°, also reported as mp 26.5°, Considine, J. Org. Chem. 25, 671 (1960). bp 225-226°, bp8 92-93°. d 0.99. nD22 1.4623. [a]D +44.38°, Haller, Compt. Rend. 109, 29 (1889); [a]D +41.2°, Considine, loc. cit.; aD14 +44.72° (neat), Shishido, loc. cit. Very slightly sol in water; sol in alcohol, ether.
Melting point: mp 29°; mp 26.5°, Considine, J. Org. Chem. 25, 671 (1960)
Boiling point: bp 225-226°; bp8 92-93°
Optical Rotation: [a]D +44.38°, Haller, Compt. Rend. 109, 29 (1889); [a]D +41.2°, Considine, loc. cit.; aD14 +44.72° (neat), Shishido, loc. cit
Index of refraction: nD22 1.4623
Density: d 0.99
 
Derivative Type: l-Form
Properties: Crystals, mp 27°. bp14 103°. [a]D -44.45°, Haller, loc. cit.; [a]D -42.0°, Considine, loc. cit.
Melting point: mp 27°
Boiling point: bp14 103°
Optical Rotation: [a]D -44.45°, Haller, loc. cit.; [a]D -42.0°, Considine, loc. cit
 
Derivative Type: dl-Form
Properties: Crystals, mp 7.0°, Considine, loc. cit.
Melting point: mp 7.0°, Considine, loc. cit