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CAS No 83-85-2 , 2H,4H-Benzo[1,2-b:4,3-c']dipyran-2,6(8H)-dione,9,10-dihydro-5-hydroxy-4,8,8-trimethyl-

  • Name: 2H,4H-Benzo[1,2-b:4,3-c']dipyran-2,6(8H)-dione,9,10-dihydro-5-hydroxy-4,8,8-trimethyl-
  • Synonyms: 2H,4H-Benzo[1,2-b:4,3-c']dipyran-2,6(8H)-dione,9,10-dihydro-5-hydroxy-4,8,8-trimethyl-;Fuscin(6CI); 9,10-Dihydro-5-hydroxy-4,8,8-trimethyl-2H,4H-benzo[1,2-b,4,3-c']dipyran-2,6(8H)-dione;
  • CAS Registry Number:
  • Flash Point: 155.5°C
  • Boiling Point: 417.6°C at 760 mmHg
  • Density: 1.35g/cm3
  • Refractive index: 1.594
  • Flash Point: 155.5°C
  • Molecular Weight: 0
  • InChI: InChI=1/C15H16O5/c1-7-11-9(6-10(16)19-7)8-4-5-15(2,3)20-14(8)13(18)12(11)17/h6-7,16H,4-5H2,1-3H3
  • Molecular Formula: C15H16 O5
  • Molecular Structure:CAS No:83-85-2 2H,4H-Benzo[1,2-b:4,3-c']dipyran-2,6(8H)-dione,9,10-dihydro-5-hydroxy-4,8,8-trimethyl-

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83-85-2 Fuscin

  • Fuscin, Min 99%
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83-85-2 FUSCIN

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References of 2H,4H-Benzo[1,2-b:4,3-c']dipyran-2,6(8H)-dione,9,10-dihydro-5-hydroxy-4,8,8-trimethyl-
Title: Fuscin
CAS Registry Number: 83-85-2
CAS Name: 9,10-Dihydro-5-hydroxy-4,8,8-trimethyl-2H,4H-benzo[1,2-b:4,3-c￠]dipyran-2,6(8H)-dione
Molecular Formula: C15H16O5
Molecular Weight: 276.28
Percent Composition: C 65.21%, H 5.84%, O 28.96%
Literature References: Antibacterial pigment produced by the fungus Oidiodendron fuscom Robak: Michael, Biochem. J. 42, XL; 43, 528 (1948). Derivatives and degradation products: Birkinshaw et al., ibid. 48, 66 (1951). Structure and synthesis: Birch, Chem. Ind. (London) 1955, 682; Barton, Hendrickson, J. Chem. Soc. 1956, 1028. Alternate synthesis: Pyuskyulev et al., Tetrahedron 29, 2849 (1973). Biosynthesis: Birch, Ciba Found. Symp. Quinones Electron Transp. 1960, 233; Birch et al., J. Chem. Soc. 1965, 1231.
Properties: Orange-colored, diamond-shaped plates from alc, mp 230°. uv max: 355, 283 nm (e 27,600; 1000). Practically insol in water, petr ether. Sol in chloroform, acetone, ethyl acetate, acetic acid, ether, benzene. Slightly sol in cold ethanol, more sol in hot ethanol. Dissolves in aq solns of alkali hydroxides and pyridine with an intense purple color. Easily reduced by hydrosulfite or other reducing agents to the colorless dihydrofuscin, C15H18O5, mp 206°, which is also found in the metabolic soln from the fungus grown on Czapek-Dox medium.
Melting point: mp 230°; mp 206°
Absorption maximum: uv max: 355, 283 nm (e 27,600; 1000)
 
 
Status: This monograph has been retired and is no longer subject to revision or update.