Home > Name List By other > (6aS)-1,10-dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de, g]quinoline-2,9-diol

CAS No 476-70-0 , (6aS)-1,10-dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,
g]quinoline-2,9-diol

  • Name: (6aS)-1,10-dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,
    g]quinoline-2,9-diol
  • Synonyms: Uniboldina;(6aS)-1,10-dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,
    g]quinoline-2,9-diol; 1,10-Dimethoxy-2,9-dihydroxyaporphine; 476-70-0; (S)-Boldine; EINECS 207-509-9; NSC 65689; Boldin; Boldine chloroform;
  • CAS Registry Number:
  • Transport: 1544
  • Melting Point: 162-164 ºC
  • Density: 1.29 g/cm3
  • Refractive index: 1.638
  • Safety Statements: R22
  • Hazard Symbols: Xn: Harmful;
  • EINECS: 207-509-9
  • Molecular Weight: 327.37434
  • InchiKey: LZJRNLRASBVRRX-ZDUSSCGKSA-N
  • InChI: InChI=1S/C19H21NO4/c1-20-5-4-10-7-15(22)19(24-3)18-12-9-16(23-2)14(21)8-
    11(12)6-13(20)17(10)18/h7-9,13,21-22H,4-6H2,1-3H3/t13-/m0/s1
  • Risk Statements: R22
  • Molecular Formula: C19H21NO4
  • Molecular Structure:CAS No:476-70-0 (6aS)-1,10-dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,<br />g]quinoline-2,9-diol
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476-70-0 Boldine

  • Boldine, min 98% (titr)
  • United States INDOFINE Chemical Co., Inc. [Manufacturer]
  • Tel: (908) 359-6778
  • Fax: (908) 359-1179
  • Address: 121 Stryker Lane
    Bldg 30, Suite 1
    Hillsborough, NJ 08844 null,nullUnited States
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476-70-0 Boldine

  • Boldine, Min 99%
  • China Finechemie Co., Ltd. [Manufacturer]
  • Tel: +86-23-99186710
  • Fax: +86-23-99186729
  • Address: 28th Floor Mordern Building,New-Tech Zone400020 ChongqingCHINA Chongqing,nullChina
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476-70-0 BOLDINE(RG)

  • BOLDINE(RG)1,10-Dimethoxy-2,9-dihydroxyaporphine
  • United States ChromaDex Inc. [Manufacturer]
  • Tel: 949-419-0288
  • Fax: 949-419-0294
  • Address: ChromaDex Inc.
    10005 Muirlands Blvd. Suite G - First Floor
    Irvine, CA 92618 null,nullUnited States
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476-70-0 Boldine

  • China Shanghai Xunxin Chemical Co., Ltd [Manufacturers]
  • Tel: +86-(21)-38218795
  • Fax: +86-(21)-38218795
  • Address: 580 Lane, Kanghong Road, Pudong New District, Shanghai 201315, Shanghai,ShanghaiChina
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476-70-0 Boldine

  • China GL Biochem (Shanghai) Ltd. [Distributor/Wholesaler]
  • Tel: +86-(21)-61263306
  • Fax: +86-(21)-61263300
  • Address: 519 Zi Yue Road, Shanghai, China 200241, ShangHai,ShangHaiChina
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476-70-0 Boldine

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476-70-0 Boldine

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476-70-0 (+)-boldine

  • China BioBioPha Co., Ltd. [Manufacturer]
  • Tel: +86-871-5217109
  • Fax: +86-871-5217109
  • Address: 132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences null,nullChina
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476-70-0 Boldine

  • China Laiwu Hehui Chemical Co.,Ltd. null
  • Tel: +86-(531)-88772589
  • Fax: +86-(531)-88772589
  • Address: Huashan Rd., Jinan City, Shandong 250000, null,nullChina
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476-70-0 (+)-boldine

  • China GL Biochem (Shanghai) Co., Ltd. [Manufacturers]
  • Tel: +86-21-61263307
  • Fax: +86-21-61263399
  • Address: No.519,ZiYue Road,Zizhu Science Park,Minhang District,Shanghai,China Shanghai,ShanghaiChina
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References of (6aS)-1,10-dimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,
g]quinoline-2,9-diol
Title: Boldine
CAS Registry Number: 476-70-0
CAS Name: 5,6,6a,7-Tetrahydro-1,10-dimethoxy-6-methyl-4H-dibenzo[de,g]quinoline-2,9-diol
Synonyms: 1,10-dimethoxy-6aa-aporphine-2,9-diol; 1,10-dimethoxy-2,9-dihydroxyaporphine; 2,6-dihydroxy-3,5-dimethoxyaporphine
Molecular Formula: C19H21NO4
Molecular Weight: 327.37
Percent Composition: C 69.71%, H 6.47%, N 4.28%, O 19.55%
Literature References: Isoln from boldo (Peumus boldus Molina, Monimiaceae): Bourgoin, Verne, J. Pharm. Chim. 16, 191 (1872); from Laurelia novaezelandiae A. Cunn.: Bernauer, Helv. Chim. Acta 50, 1583 (1967). Structure: Warnat, Ber. 58, 2768; 59, 85 (1926); Sp?th, Tharrer, ibid. 66, 904 (1933); Schlittler, ibid. 988. Synthesis of dl-form: S. M. Kupchan et al., Chem. Commun. 1976, 91. Biosynthetic study: D. S. Bhakuni et al., J. Chem. Soc. Perkin Trans. 1 1977, 706. Detailed description of the boldo brush, its ingredients and pharmacological properties: H. Schindler, Arzneim.-Forsch. 7, 747 (1957).
 
Derivative Type: d-Form
Properties: Crystals from ether. mp 162-164°. [a]D25 +127° (c = 0.1 in alcohol). Very slightly sol in water or ether; sol in alcohol, chloroform, dil acids.
Melting point: mp 162-164°
Optical Rotation: [a]D25 +127° (c = 0.1 in alcohol)
 
Derivative Type: d-Form hydrochloride
Properties: Crystals from methanol-ether and methanol, mp 212-220°.
Melting point: mp 212-220°
 
Derivative Type: dl-Form
Properties: mp 159-162°.
Melting point: mp 159-162°
 
Derivative Type: Dimethyl ether see Glaucine
 
NOTE: Boldine is used as an ingredient in choleretics and laxatives. The total alkaloids from boldo are also marketed as a grayish-white to grayish-yellow, bitter powder; almost insol in water. Sol in alc, chloroform, slightly in ether.